Full metadata record
| DC pole | Hodnota | Jazyk |
|---|---|---|
| dc.contributor.author | Wörsching, Matthias P.B. | |
| dc.contributor.author | Fricke, Sarah Kristin | |
| dc.contributor.author | Minár, Jan | |
| dc.contributor.author | Niklaus, Robin | |
| dc.contributor.author | Hoch, Constantin | |
| dc.date.accessioned | 2020-08-31T10:00:24Z | - |
| dc.date.available | 2020-08-31T10:00:24Z | - |
| dc.date.issued | 2019 | |
| dc.identifier.citation | WÖRSCHING, M. P., FRICKE, S. K., MINÁR, J., NIKLAUS, R., HOCH, C. Ba6(MN4)N2–x (M = MoVI/TaV), a Subvalent Nitridometalate with Perovskite-like Crystal Structure. Zeitschrift fur anorganische und allgemeine Chemie, 2019, roč. 645, č. 3, s. 278-283. ISSN 0044-2313. | en |
| dc.identifier.issn | 0044-2313 | |
| dc.identifier.uri | 2-s2.0-85056359893 | |
| dc.identifier.uri | http://hdl.handle.net/11025/39560 | |
| dc.format | 6 s. | cs |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | en | en |
| dc.publisher | Wiley | en |
| dc.relation.ispartofseries | Zeitschrift Fur Anorganische Und Allgemeine Chemie | de |
| dc.rights | Plný text není přístupný. | cs |
| dc.rights | © Wiley | en |
| dc.title | Ba6(MN4)N2–x (M = MoVI/TaV), a Subvalent Nitridometalate with Perovskite-like Crystal Structure | en |
| dc.type | článek | cs |
| dc.type | article | en |
| dc.rights.access | closedAccess | en |
| dc.type.version | publishedVersion | en |
| dc.description.abstract-translated | The subvalent nitridometalate Ba-6[(Mo1-xTax)N-4]N-0.86 was prepared from mixtures of Mo powder with Ba, Na, and Ba2N at 600 degrees C in Ta ampoules. It crystallizes in space group Cmcm with a = 11.672(3), b = 10.177(2) and c = 10.8729(19) angstrom. Its crystal structure exhibits an orthorhombically distorted Perovskite topology with [Ba6N] building units forming the ReO3-type lattice via common vertices, and the nitridometalate anions occupying half of the available distorted cuboctahedral interstices. [MN4] anions show statistically mixed occupancy of M by Mo-VI and Ta-V. They show no notable deviation from nitridometalate anions in known ionic nitridomolybdates and -tantalates, and the metrics of the [Ba6N] octahedra correspond to those found in similar subvalent compounds. The nitrogen atom position centering the [Ba6N] octahedra is underoccupied. Band structure calculations corroborate the subvalent character of the compound and the two individual anionic structural building units. | en |
| dc.subject.translated | Nitridometalates | en |
| dc.subject.translated | Barium | en |
| dc.subject.translated | Crystal structure | en |
| dc.subject.translated | Subvalent compounds | en |
| dc.subject.translated | Perovskite | en |
| dc.identifier.doi | 10.1002/zaac.201800400 | |
| dc.type.status | Peer-reviewed | en |
| dc.identifier.document-number | 459876900022 | |
| dc.identifier.obd | 43929863 | |
| dc.project.ID | EF15_003/0000358/Výpočetní a experimentální design pokročilých materiálů s novými funkcionalitami | cs |
| Vyskytuje se v kolekcích: | Články / Articles (RAM) OBD | |
Soubory připojené k záznamu:
| Soubor | Velikost | Formát | |
|---|---|---|---|
| Minar_WFM+18_ZAAC_Hoch.pdf | 970,29 kB | Adobe PDF | Zobrazit/otevřít Vyžádat kopii |
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