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dc.contributor.authorNešpůrek, Stanislav
dc.contributor.authorKuberský, Petr
dc.contributor.authorPolanský, Radek
dc.contributor.authorTrchová, Miroslava
dc.contributor.authorŠebera, Jakub
dc.contributor.authorSychrovský, Vladimír
dc.date.accessioned2022-02-28T11:00:25Z-
dc.date.available2022-02-28T11:00:25Z-
dc.date.issued2022
dc.identifier.citationNEŠPŮREK, S. KUBERSKÝ, P. POLANSKÝ, R. TRCHOVÁ, M. ŠEBERA, J. SYCHROVSKÝ, V. Raman spectroscopy and DFT calculations of PEDOT:PSS in a dipolar field. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2022, roč. 24, č. 1, s. 541-550. ISSN: 1463-9076cs
dc.identifier.issn1463-9076
dc.identifier.uri2-s2.0-85121864296
dc.identifier.urihttp://hdl.handle.net/11025/47034
dc.format10 s.cs
dc.format.mimetypeapplication/pdf
dc.language.isoenen
dc.publisherRoyal Society of Chemistryen
dc.relation.ispartofseriesPhysical Chemistry Chemical Physicsen
dc.rights© the Owner Societiesen
dc.titleRaman spectroscopy and DFT calculations of PEDOT:PSS in a dipolar fielden
dc.typečlánekcs
dc.typearticleen
dc.rights.accessclosedAccessen
dc.type.versionpublishedVersionen
dc.description.abstract-translatedThe conductive polymer-electrolyte interface plays an important role in many electrochemical devices. An unusual situation arises when a solvent-free ionic liquid (SF-IL) is used as the electrolyte because it behaves as a molten salt rather than an electrolyte solution. On the basis of Raman spectra, it was found that the presence of ion pairs of SF-IL in the vicinity of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) results in a decrease in the oxidation level of the polymer and an increase in the HOMO-LUMO gap. The process of polymer “dedoping” and the modification of the electronic structure of the polymer are illustrated by quantum chemical calculations.en
dc.subject.translatedchemical modificationen
dc.subject.translatedelectronic structureen
dc.subject.translatedionic liquidsen
dc.subject.translatedpolyelectrolytesen
dc.subject.translatedquantum chemistryen
dc.identifier.doi10.1039/d1cp03899k
dc.type.statusPeer-revieweden
dc.identifier.document-number729859200001
dc.identifier.obd43934716
dc.project.IDGA20-03913S/Organické senzory plynů - nové struktury, jejich vlastnosti a funkcecs
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