Title: | Renormalization of the valence and conduction bands of (C6H5C2H4NH3)(2)PbI4 hybrid perovskite |
Authors: | Lee, Min-I Khan, Saleem Ayaz Mrezguia, Hela Barragán, Ana Nair, Maya N. Khelidj, Hamza Ksari, Younal Giovanelli, Luca Themlin, Jean-Marc Lédée, Ferdinand Trippé-Allard, Gaëlle Deleporte, Emmanuelle Taleb-Ibrahimi, Amina Minár, Jan Tejeda, Antonio |
Citation: | LEE, M. KHAN, SA. MREZGUIA, H. BARRAGÁN, A. NAIR, MN. KHELIDJ, H. KSARI, Y. GIOVANELLI, L. THEMLIN, J. LÉDÉE, F. TRIPPÉ-ALLARD, G. DELEPORTE, E. TALEB-IBRAHIMI, A. MINÁR, J. TEJEDA, A. Renormalization of the valence and conduction bands of (C6H5C2H4NH3)(2)PbI4 hybrid perovskite. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2021, roč. 54, č. 36, s. nestránkováno. ISSN: 0022-3727 |
Issue Date: | 2021 |
Publisher: | IOP Publishing |
Document type: | článek article |
URI: | 2-s2.0-85110325801 http://hdl.handle.net/11025/47044 |
ISSN: | 0022-3727 |
Keywords in different language: | 2D hybrid organic-inorganic perovskites;angle-resolved photoemission spectroscopy;inverse photoemission spectroscopy;spin–orbit coupling;k-resolved band structures;phenylethylammonium lead iodine;(C6H5C2H4NH3)2PbI4 |
Abstract in different language: | Quasi two-dimensional hybrid organic-inorganic perovskites (HOIPs) have been rediscovered recently for photovoltaics due to a higher stability than other HOIPs. We focus here on the electronic structure of the 2D perovskite (C6H5C2H4NH3)2PbI4. We perform an experimental k-resolved determination of the valence and conduction bands by angle-resolved photoemission spectroscopy (ARPES) and inverse photoemission spectroscopy (IPES). The experimental and theoretical dispersions are compared. The valence band width is in agreement with that of renormalized theoretical bands, while no significative renormalization is observed for the conduction band. The effect of the spin–orbit coupling in the conduction band is also experimentally observed. |
Rights: | © IOP Publishing |
Appears in Collections: | Články / Articles (RAM) OBD |
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KHAN_LKM+21_Lee_2021_J._Phys._D__Appl._Phys._54_365301.pdf | 1,7 MB | Adobe PDF | View/Open |
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